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KMR ADVICE

GPAT / NIPER Question Bank Series

Mr. K. Mallikarjuna Reddy

Associate Professor, M. Pharma (Pharmacology)

kmradvice.com

🎯 GPAT QUESTION BANK β€” Subject-wise Practice

Interactive MCQs with full explanations (why right + why each wrong)

BP601T Β· MEDICINAL CHEMISTRY III

GPAT Question Bank β€” 90+ MCQs

Antimicrobials Β· Antineoplastics Β· Antiviral Β· Antimalarial Β· Antiprotozoal Β· Anthelmintic

πŸ“– HOW TO USE

🟒 Click option β†’ correct turns green, wrong pick red, explanation opens.

🏷️ GPAT Past = confirmed past-GPAT topic · Pattern Practice = same-pattern practice MCQ.

πŸ“Š Live score bar. πŸ” Reset to try again.

πŸ“‹ MCQ DISTRIBUTION β€” variable per unit importance

UnitTopicMCQ count
IAntibiotics β€” Ξ²-lactams (penicillins, cephalosporins, carbapenems, monobactams), aminoglycosides, tetracyclines~ 22
IIAntibiotics (contd.) β€” macrolides, chloramphenicol, sulphonamides, quinolones/fluoroquinolones, anti-TB, anti-fungals~ 22
IIIAntiviral drugs & antiprotozoals (amoebicides, anti-malarial, leishmania, trypanosomes)~ 18
IVAnthelmintics, urinary tract antiseptics, anti-leprotics~ 10
VAnti-neoplastic agents (alkylating, antimetabolites, antibiotics, plant products, targeted) + immunomodulators~ 18
0Attempted
0Correct
0Wrong
0%Accuracy
πŸ“Š Filter by Unit:
UNIT I
Ξ²-Lactams, Aminoglycosides, Tetracyclines (Q1 – Q22)
1
Core nucleus of penicillins is: Most Probable
  • ACephem
  • B6-Aminopenicillanic
  • CMacrolactone
  • DPurine

πŸ“˜ Explanation

βœ” Correct β€” B: 6-APA = penam nucleus β€” 4-membered Ξ²-lactam + 5-membered thiazolidine ring sharing N-C bond. Commercial semi-synthetic penicillins made by (1) fermenting 6-APA from Penicillium chrysogenum culture (penicillin-G acylase cleaves benzyl group), OR (2) chemical enzymatic acylation with appropriate acid chloride. Mechanism: Ξ²-lactam ring mimics D-Ala-D-Ala of peptidoglycan, irreversibly acylates Transpeptidase (PBP = Penicillin-Binding Protein) β†’ blocks peptidoglycan cross-linking β†’ bacterial cell wall weakening β†’ osmotic lysis β†’ bactericidal.
✘ A wrong: Cephem = cephalosporin nucleus (7-ACA with 6-membered dihydrothiazine).
✘ C wrong: Macrolides.
✘ D wrong: Purine = nucleosides.
2
Penicillin is inactivated in stomach because: GPAT 2019
  • ADenatured by pepsin
  • BOxidised
  • CΞ²-lactam ring is acid-labile
  • DNot inactivated

πŸ“˜ Explanation

βœ” Correct β€” C: Penicillin G (benzylpenicillin) β€” acid-labile because electron-donating aromatic CHβ‚‚ side chain increases rate of proton-mediated Ξ²-lactam opening. Semi-synthetic acid-stable penicillins: penicillin V (phenoxymethyl, -OCHβ‚‚- EWG); ampicillin (Ξ±-aminobenzyl); amoxicillin (Ξ±-amino-4-hydroxybenzyl); dicloxacillin (isoxazolyl). Ξ²-Lactamase-stable (anti-staphylococcal): methicillin (2,6-dimethoxybenzyl), oxacillin, cloxacillin, nafcillin β€” bulky R group sterically hinders Ξ²-lactamase. Extended-spectrum: ampicillin + amoxicillin (G⁻ coverage); piperacillin, ticarcillin (Pseudomonas).
✘ A/B wrong: Mechanism incorrect.
✘ D wrong: Acid inactivation is real.
3
Ξ²-Lactamase inhibitors include: Most Probable
  • AClavulanic acid
  • BAminoglycosides
  • CQuinolones
  • DMacrolides

πŸ“˜ Explanation

βœ” Correct β€” A: Old Ξ²-lactam-based inhibitors (irreversible "suicide" inhibitors): clavulanic acid (from Streptomyces clavuligerus) + amoxicillin (Augmentin) or ticarcillin (Timentin); sulbactam + ampicillin (Unasyn), sulbactam + cefoperazone; tazobactam + piperacillin (Zosyn/Tazact). New non-Ξ²-lactam inhibitors β€” DBO class: avibactam (+ ceftazidime = Avycaz, + aztreonam = Zaviam, + ceftaroline); boronic-acid class: vaborbactam (+ meropenem = Vabomere); relebactam (+ imipenem/cilastatin = Recarbrio). Enmetazobactam, xeruborbactam, taniborbactam β€” investigational. Cover Ambler classes A, C, some D, NOT class B metallo-Ξ²-lactamases (MBLs).
✘ B/C/D wrong: Different classes.
4
Cephalosporin nucleus: GPAT 2018
  • A6-APA
  • B7-Aminocephalosporanic
  • CMacrolactone
  • DErythronolide

πŸ“˜ Explanation

βœ” Correct β€” B: 7-ACA from cephalosporin-C (produced by Acremonium chrysogenum/Cephalosporium). Historical generations β€” each with wider G⁻ coverage: 1st gen (cefazolin, cefalexin) β€” broad G⁺, limited G⁻; 2nd gen (cefuroxime, cefoxitin) β€” more G⁻ + anaerobes (cefoxitin is cephamycin); 3rd gen (ceftriaxone, cefotaxime, ceftazidime, cefoperazone) β€” extended G⁻ incl. Pseudomonas (ceftazidime); 4th gen (cefepime) β€” broad; 5th gen (ceftaroline, ceftobiprole) β€” active against MRSA (binds PBP2a). Siderophore cephalosporin: cefiderocol β€” uses iron transport to enter CRE.
✘ A wrong: 6-APA = penicillin.
✘ C wrong: Macrolides.
✘ D wrong: Erythromycin nucleus.
5
Carbapenem general structure: Most Probable
  • AΞ²-lactam fused with thiazolidine
  • BΞ²-lactam alone without fused ring
  • CΞ²-lactam fused with 5-membered pyrroline
  • DΞ²-lactam fused with 6-membered ring like cephalosporin

πŸ“˜ Explanation

βœ” Correct β€” C: Carbapenems: imipenem (+ cilastatin to inhibit DHP-I renal deactivation), meropenem, ertapenem, doripenem, faropenem, tebipenem (orally bioavailable prodrug). Broadest-spectrum Ξ²-lactams β€” cover G⁺, G⁻ including Pseudomonas (except ertapenem), anaerobes, ESBL-producers, some AmpC. NOT active against MRSA, Enterococcus faecium, Stenotrophomonas, MBL-producing CRE (NDM, VIM, IMP). Adverse: seizures (imipenem > meropenem; avoid in epilepsy + high dose). Reserved for serious/resistant infections β€” use carefully to avoid selection for CRE.
✘ A wrong: Penam.
✘ B wrong: Monobactam.
✘ D wrong: Cephem.
6
Aztreonam (monobactam) is active against: Most Probable
  • AGram-positive
  • BAnaerobes
  • CFungi
  • DAerobic Gram-negative

πŸ“˜ Explanation

βœ” Correct β€” D: Aztreonam = only clinically used monobactam; monocyclic Ξ²-lactam (no fused ring). Spectrum = narrow G⁻ including Pseudomonas aeruginosa, Enterobacteriaceae, H. influenzae, Neisseria. No G⁺ or anaerobic activity. Key use: patients with severe penicillin allergy needing G⁻ coverage β€” structural differences with penicillins mean rare cross-reactivity (except ceftazidime, because of same aminothiazolyl side chain). Resistant to most penicillinases but susceptible to ESBLs; combined with avibactam (aztreonam-avibactam) = active against MBL + KPC producing CRE.
✘ A/B/C wrong: Not in spectrum.
7
Streptomycin is obtained from: GPAT 2020
  • AStreptomyces griseus
  • BPenicillium
  • CE. coli
  • DSynthetic

πŸ“˜ Explanation

βœ” Correct β€” A: Streptomycin contains 3 saccharide units: streptidine (guanidino group), streptose, N-methyl-L-glucosamine. Bactericidal; binds 30S ribosomal subunit β†’ misreading & inhibition of protein synthesis. Concentration-dependent killing; post-antibiotic effect. Uses: TB (2nd-line now), plague, tularaemia, brucellosis. ADR: ototoxicity (vestibular > cochlear), nephrotoxicity, NMJ blockade (myasthenia β€” contraindication). Natural aminoglycosides: gentamicin (Micromonospora), tobramycin, neomycin, kanamycin. Semi-synthetic: amikacin (6'-CH₃ + L-HABA at C1 β€” resists inactivation), netilmicin.
✘ B wrong: Penicillium = penicillins, griseofulvin.
✘ C wrong: E. coli is target.
✘ D wrong: Natural product.
8
Amikacin is resistant to most aminoglycoside-modifying enzymes due to: GPAT 2020
  • AIts amino groups
  • BL-Ξ±-hydroxyaminobutyric acid
  • CLack of OH groups
  • DLipid solubility

πŸ“˜ Explanation

βœ” Correct β€” B: Amikacin = semi-synthetic from kanamycin A; L-HABA at N1 confers resistance to major aminoglycoside-modifying enzymes (acetyltransferases AAC, phosphotransferases APH, adenyltransferases ANT) by steric hindrance. Arbekacin similar mechanism. Plazomicin (approved 2018) β€” next-gen AG against CRE, KPC, ESBL producers. All AGs share same ribosomal target; resistance via enzymatic modification (AAC, APH, ANT), efflux, target methylation (16S rRNA methyltransferase β€” ArmA, RmtB β†’ pan-resistance). Therapeutic drug monitoring (TDM): peak & trough concentrations; once-daily dosing preferred for concentration-dependent killing + reduced toxicity.
✘ A/C/D wrong: Not the mechanism.
9
Tetracycline basic ring system: GPAT 2019
  • A3 linear rings
  • B5 linear rings
  • COctahydronaphthacene
  • D6 rings

πŸ“˜ Explanation

βœ” Correct β€” C: Tetra-cycline = 4 rings. First discovered: chlortetracycline (Aureomycin, 1948, Streptomyces aureofaciens); oxytetracycline (Terramycin, 1950, S. rimosus); tetracycline (semi-synthetic, 1953); demeclocycline (natural, S. aureofaciens mutant); methacycline; doxycycline & minocycline (semi-synthetic 2nd gen); tigecycline (glycylcycline, 3rd gen, 2005); eravacycline (2018). Mechanism: bacteriostatic; binds 30S ribosomal subunit at A site β†’ blocks aminoacyl-tRNA entry. Chelate divalent/trivalent cations (Ca²⁺, Mg²⁺, Al³⁺, Fe²⁺) β†’ reduced absorption with dairy/antacid; deposit in growing bone/teeth β†’ CI children < 8 yrs & pregnancy.
✘ A/B/D wrong: Wrong ring count.
10
Doxycycline differs from tetracycline in: GPAT 2019
  • AHigher lipid solubility
  • BLower potency
  • COnly injectable
  • DNo effect on bone

πŸ“˜ Explanation

βœ” Correct β€” A: Doxycycline = Ξ±-6-deoxytetracycline; 2nd-gen with superior PK. Dose 100 mg BD (or 200 mg OD). Uses: atypical pneumonia (Mycoplasma, Chlamydia, Legionella), Rocky Mountain spotted fever & other Rickettsia, Lyme disease (Borrelia burgdorferi), cholera, brucellosis, acne (anti-inflammatory sub-antibacterial dose), malaria prophylaxis (chloroquine-resistant Plasmodium falciparum), periodontitis (sub-antimicrobial for MMP inhibition). Minocycline = methylamino analogue β€” best BBB penetration (used in neurological infections; pigmentation ADR); also for acne, Mycobacterium leprae, Nocardia.
✘ B wrong: Similar potency.
✘ C wrong: Oral mainstay.
✘ D wrong: Still deposits in bone/teeth (less).
11
Fleming discovered penicillin in: GPAT 2019
  • A1920
  • B1928
  • C1942
  • D1910

πŸ“˜ Explanation

βœ” Correct β€” B: Fleming (St. Mary's Hospital, London) β€” serendipitous observation. Ushered "antibiotic era." Production issues (low yield from P. notatum) solved at Oxford (Florey, Chain, Heatley) β†’ P. chrysogenum (higher-yielding) + deep-tank fermentation + corn-steep liquor medium β†’ industrial-scale by WWII. First human patient: Albert Alexander (1941, near-death from septicaemia β€” recovered then died when supply ran out). Fleming, Florey, Chain = Nobel 1945.
✘ A/C/D wrong: Wrong years.
12
Chloramphenicol structural features: GPAT 2018
  • AMacrolactone
  • BTetracyclic
  • CNitrobenzene
  • DAminoglycoside

πŸ“˜ Explanation

βœ” Correct β€” C: Chloramphenicol (from Streptomyces venezuelae 1947; now fully synthetic). Mechanism: binds 50S ribosomal subunit at peptidyl transferase site β†’ blocks peptide bond formation β†’ bacteriostatic. Broad-spectrum. Uses (narrow now because of ADR): typhoid (ceftriaxone preferred now), meningitis (alternative), anaerobic, rickettsial. ADR: reversible bone marrow suppression (dose-dependent); idiosyncratic aplastic anaemia (1 in 25,000-40,000; fatal; unpredictable) β€” limits use; "Gray baby syndrome" in neonates (↓ UGT conjugation β†’ accumulation β†’ vasomotor collapse). Thiamphenicol (less aplastic anaemia); chloramphenicol succinate (IV prodrug); palmitate (oral suspension).
✘ A/B/D wrong: Different classes.
13
Vancomycin mechanism: Most Probable
  • AGlycopeptide
  • BInhibits topoisomerase
  • CBlocks 30S ribosome
  • DInhibits dihydrofolate reductase

πŸ“˜ Explanation

βœ” Correct β€” A: Vancomycin (Amycolatopsis orientalis, 1955 β€” old drug, still front-line for MRSA) binds by 5 H-bonds to D-Ala-D-Ala. Resistance mechanism in VRE/VRSA: alter terminus to D-Ala-D-Lactate (vanA, vanB β€” inducible) or D-Ala-D-Ser (vanC β€” intrinsic in E. gallinarum/casseliflavus) β†’ ↓ affinity 1000Γ—. IV for systemic (not oral-absorbed); oral for C. difficile colitis (acts locally). ADR: "red man syndrome" (histamine release on rapid IV); nephrotoxicity (AUC > 600 mgΒ·h/L); ototoxicity. Target AUC/MIC > 400. Related: teicoplanin, dalbavancin, oritavancin, telavancin (lipoglycopeptides β€” bactericidal + membrane disruption).
✘ B wrong: Quinolones.
✘ C wrong: Aminoglycosides/tetracyclines.
✘ D wrong: Trimethoprim/sulphonamides.
14
Penicillin-G is typically administered: GPAT 2019
  • AOrally
  • BTopically
  • CRectally
  • DIM or IV

πŸ“˜ Explanation

βœ” Correct β€” D: Penicillin G (crystalline Na/K salt) β€” IV; short tΒ½ (30 min). Procaine penicillin G β€” IM suspension; 12-24 h duration. Benzathine penicillin G β€” IM; very prolonged (2-4 weeks) β†’ single-shot treatment of syphilis (all stages except neurosyphilis which requires IV aq penicillin); secondary prophylaxis for rheumatic fever. Oral Pen V (phenoxymethyl) β€” acid-stable; used for strep pharyngitis, step 1 in rheumatic fever prevention. Uses: meningococcus, streptococci (all), Treponema pallidum, Listeria (with gentamicin), Actinomyces. Resistance common in Staphylococcus (95%+ produce Ξ²-lactamase) and increasingly Pneumococcus (via altered PBP2x).
✘ A/B/C wrong: Not main routes.
15
Methicillin is unique among penicillins because: GPAT 2019
  • AAcid stable
  • BΞ²-Lactamase-resistant
  • CBroad spectrum
  • DActive against Pseudomonas

πŸ“˜ Explanation

βœ” Correct β€” B: "Anti-staphylococcal penicillins" or "isoxazolyl penicillins" (cloxacillin, oxacillin, flucloxacillin, dicloxacillin) β€” bulky side chains. MRSA mechanism: mecA gene encodes PBP2a (=PBP2'), a low-affinity PBP β€” all Ξ²-lactams lose activity except newer 5th-gen cephalosporins (ceftaroline, ceftobiprole which bind PBP2a). Also, MRSA isolates are resistant to ALL standard Ξ²-lactams. Treatment: vancomycin / linezolid / daptomycin / ceftaroline / tigecycline (AUC/MIC pharmacodynamics important).
✘ A/C/D wrong: Not the distinguishing feature.
16
Ampicillin differs from penicillin-G in: GPAT 2019
  • AMore active against MRSA
  • BΞ²-lactamase stability
  • CBroader Gram-negative spectrum
  • DBetter CNS penetration

πŸ“˜ Explanation

βœ” Correct β€” C: Ampicillin = aminobenzylpenicillin. Amoxicillin = Ξ±-amino-4-hydroxybenzylpenicillin; better oral (~ 90 %), same spectrum as ampicillin. Amoxicillin-clavulanate = popular combination. Ampicillin ADR: rash (esp. with EBV β€” Mono rash), diarrhoea (↑ normal flora disruption vs amoxicillin). Still Ξ²-lactamase susceptible β†’ not effective against Ξ²-lactamase-producing strains without inhibitor. Ampicillin-sulbactam = IV combo.
✘ A wrong: Not active against MRSA.
✘ B wrong: β-lactamase-labile.
✘ D wrong: Similar CNS penetration.
17
Ceftriaxone is a 3rd-gen cephalosporin with: GPAT 2018
  • ALong tΒ½
  • BShort tΒ½
  • COnly IV
  • DOnly topical

πŸ“˜ Explanation

βœ” Correct β€” A: Ceftriaxone β€” IV/IM once daily. Does not require renal adjustment. CI: biliary sludging β†’ avoid in neonates + calcium-containing IV solutions (fatal precipitates). DOC: community-acquired meningitis, gonorrhoea (single IM 500 mg), typhoid (ceftriaxone vs ciprofloxacin β€” widespread resistance now), CAP, endocarditis (with vancomycin), chancroid, severe otitis. Cefotaxime = similar spectrum, shorter tΒ½, no biliary sludging. Ceftazidime = anti-pseudomonal 3rd-gen (loses anti-Gram-positive coverage compared to ceftriaxone).
✘ B/C/D wrong: Not accurate.
18
Imipenem is administered with cilastatin because: Most Probable
  • AAdjuvant activity
  • BCilastatin is a dehydropeptidase-I
  • CCilastatin is antibiotic
  • DSynergistic against Pseudomonas

πŸ“˜ Explanation

βœ” Correct β€” B: Imipenem (first carbapenem, 1985) is hydrolysed by renal DHP-I β†’ nephrotoxic. Cilastatin is specific DHP-I inhibitor (not antibacterial) β†’ co-administered 1:1 as Primaxin/Tienam. Newer carbapenems β€” meropenem, ertapenem, doripenem β€” have 1Ξ²-methyl substituent that makes them DHP-I-stable β†’ no cilastatin needed. Meropenem now preferred (fewer seizures, broader G⁻). Carbapenems reserved for serious MDR infections; CRE (via KPC, OXA-48, NDM, VIM, IMP) is growing problem globally β€” need new agents (ceftazidime-avibactam, meropenem-vaborbactam, cefiderocol, plazomicin etc.).
✘ A/C/D wrong: Incorrect.
19
Tigecycline is classified as: Most Probable
  • AMacrolide
  • BAminoglycoside
  • CFluoroquinolone
  • DGlycylcycline

πŸ“˜ Explanation

βœ” Correct β€” D: Tigecycline approved 2005 (Tygacil). Steric bulk at C9 overcomes tet(M) & tet(B) efflux/ribosomal protection β€” active against tetracycline-resistant strains. FDA black-box: ↑ mortality vs comparators in trials (attributed to wider use in MDR septicaemia). Not effective in bloodstream infection alone. Eravacycline (Xerava, 2018) β€” similar class, IV+oral prodrug. Omadacycline (Nuzyra, 2018) β€” aminomethylcycline, oral + IV. Sarecycline β€” narrow-spectrum for acne only.
✘ A/B/C wrong: Different classes.
20
Daptomycin mechanism: Most Probable
  • ACyclic lipopeptide
  • BInhibits DNA gyrase
  • C30S ribosome binder
  • DΞ²-lactam

πŸ“˜ Explanation

βœ” Correct β€” A: Daptomycin (Cubicin, 2003) = 13-aa cyclic lipopeptide from Streptomyces roseosporus. IV 4-6 mg/kg OD. Uses: complicated skin infections, S. aureus bacteraemia (including right-sided endocarditis), VRE. NOT for pneumonia β€” inactivated by pulmonary surfactant. ADR: myopathy (monitor CPK weekly; stop statins concomitantly), eosinophilic pneumonia, peripheral neuropathy. Relatively low resistance rates. Lipoglycopeptides (telavancin, dalbavancin, oritavancin) β€” dual cell wall + membrane mechanism.
✘ B/C/D wrong: Wrong targets.
21
Linezolid class & mechanism: Most Probable
  • AMacrolide
  • BQuinolone
  • COxazolidinone
  • DΞ²-lactam

πŸ“˜ Explanation

βœ” Correct β€” C: Linezolid (Zyvox, 2000) = first-in-class oxazolidinone. Uniquely 100 % oral bioavailable β†’ IV-PO interchangeable. Active against MRSA, VRE, multi-drug-resistant TB, Nocardia. ADR: reversible myelosuppression (thrombocytopenia β†’ monitor CBC weekly, especially after 2 weeks), peripheral & optic neuropathy (long-term), lactic acidosis, serotonin syndrome (weak MAO-inhibitor β€” avoid SSRIs, triptans, meperidine), hypoglycaemia. Tedizolid (Sivextro, 2014) β€” improved oxazolidinone; once-daily, less myelosuppression.
✘ A/B/D wrong: Wrong classes.
22
Sulbactam acts as: Practice Question
  • APrimary antibiotic
  • BIrreversible Ξ²-lactamase
  • CDNA-gyrase inhibitor
  • DAminoglycoside

πŸ“˜ Explanation

βœ” Correct β€” B: Sulbactam β€” ("suicide" inhibitor) binds serine at Ξ²-lactamase active site β†’ irreversible covalent inhibition. Unique: has intrinsic anti-Acinetobacter baumannii activity (binds PBP2/3), often exploited for MDR Acinetobacter. Tazobactam (similar mechanism, piperacillin-tazobactam = Zosyn/Tazact β€” broad spectrum IV). Durlobactam β€” new DBO inhibitor + sulbactam (Xacduro 2023) for carbapenem-resistant Acinetobacter baumannii. Clavulanic acid (Amoxiclav, Augmentin) β€” oldest. All inhibit Ambler class A & some class D, NOT class C (AmpC) or B (metallo).
✘ A/C/D wrong: Not the mechanism.
UNIT II
Macrolides Β· Chloramphenicol Β· Sulphonamides Β· Quinolones Β· Anti-TB Β· Antifungals (Q23 – Q44)
23
Erythromycin core structure: GPAT 2020
  • A12-membered lactone
  • B16-membered lactone
  • C14-membered macrolactone
  • DQuinoline

πŸ“˜ Explanation

βœ” Correct β€” C: Erythromycin (1952) β€” 14-membered macrolactone. Mechanism: binds 23S rRNA of 50S ribosome β†’ inhibits translocation β†’ bacteriostatic. Uses: Legionella, Chlamydia, Mycoplasma, Bordetella pertussis, streptococci, syphilis (penicillin-allergic). ADR: GI intolerance (motilin agonism β†’ prokinetic effect β€” exploited for gastroparesis at low dose), cholestatic hepatitis, QT prolongation, ototoxicity (high dose). Drug interaction: potent CYP3A4 inhibitor β†’ ↑ levels of warfarin, theophylline, digoxin, cyclosporine. Clarithromycin = 6-O-methyl-erythromycin (improved acid stability, better absorption, similar interactions). Azithromycin = 15-membered azalide (N inserted) β€” better tissue penetration, longer tΒ½ (68 h), less interactions.
✘ A wrong: 12-membered not erythromycin.
✘ B wrong: Spiramycin / josamycin / tylosin.
✘ D wrong: Quinolone.
24
Azithromycin is: GPAT 2020
  • A15-membered azalide
  • BTetracycline analogue
  • CAminoglycoside
  • DΞ²-lactam

πŸ“˜ Explanation

βœ” Correct β€” A: Azithromycin β€” tissue concentrations exceed plasma 10-100Γ—, especially in macrophages. Uses: CAP, otitis media, sinusitis, strep pharyngitis, chlamydia (single 1 g), traveller's diarrhoea, typhoid (Salmonella Typhi in children/pregnancy), MAC prophylaxis & treatment in HIV, pertussis, cholera. COVID-19 β€” studied without strong evidence. ADR: QT prolongation (avoid with class IA/III antiarrhythmics), hepatotoxicity, hearing loss (long-term), hypertrophic pyloric stenosis in neonates < 1 month. Fewer CYP interactions than erythromycin.
✘ B/C/D wrong: Wrong classes.
25
Sulphonamides are structurally analogues of: Most Probable
  • AThymidine
  • Bp-Aminobenzoic acid
  • CCholesterol
  • DGlucose

πŸ“˜ Explanation

βœ” Correct β€” B: Sulphonamides β€” sulphanilamide prototype (Domagk 1932, Prontosil prodrug β†’ Nobel 1939); SAR: free p-NH2 essential; N1 substitution modulates activity & PK. Classification: short-acting (sulphisoxazole, sulphamethizole β€” UTI), intermediate (sulphamethoxazole β€” with TMP = cotrimoxazole), long-acting (sulphadoxine β€” malaria, Fansidar = sulphadoxine-pyrimethamine), topical (silver sulphadiazine for burns; sulphacetamide for ophthalmic). Resistance: altered DHPS, ↑ PABA, bypass. Synergy with trimethoprim (TMP, DHFR inhibitor) β€” sequential blockade of folate pathway β†’ bactericidal (cotrimoxazole). Uses: UTI, Pneumocystis jirovecii pneumonia (PCP) β€” DOC; toxoplasmosis; Nocardia; Stenotrophomonas.
✘ A/C/D wrong: Different metabolites.
26
Trimethoprim mechanism: GPAT 2020
  • ACell wall synthesis inhibition
  • B30S ribosome inhibitor
  • CSelectively inhibits BACTERIAL
  • DDNA gyrase inhibitor

πŸ“˜ Explanation

βœ” Correct β€” C: TMP = 2,4-diaminopyrimidine; selectively inhibits bacterial DHFR (converts DHF β†’ THF). Combined with sulphamethoxazole (SMX) 1:5 ratio β†’ cotrimoxazole (trim SMX 80/400 per tablet). Synergy: folate pathway blocked sequentially β†’ bactericidal. Human DHFR inhibitors: methotrexate (cancer), pyrimethamine (malaria, toxoplasmosis), proguanil (malaria, activated in vivo). ADR: nausea, rash, hyperkalaemia (ENaC inhibition similar to amiloride), megaloblastic anaemia (rare β€” reversed by folinic acid), Stevens-Johnson syndrome, G6PD haemolysis, kernicterus in neonates (bilirubin displacement), nephrotoxicity (crystalluria with sulphadiazine).
✘ A/B/D wrong: Wrong targets.
27
Fluoroquinolones' target: Most Probable
  • A50S ribosome
  • BCell wall
  • CFolate pathway
  • DDNA gyrase

πŸ“˜ Explanation

βœ” Correct β€” D: Quinolones β€” concentration-dependent killing; AUC/MIC > 125 (G⁻). Nalidixic acid (1st gen, 1960s β€” UTI only). Fluoroquinolones (F at C6, piperazine at C7): 2nd gen β€” ciprofloxacin, norfloxacin, ofloxacin (broad G⁻ + Pseudomonas); 3rd gen β€” levofloxacin (L-isomer of ofloxacin), gatifloxacin, moxifloxacin (respiratory FQ, also covers atypicals, anaerobes); 4th gen β€” trovafloxacin (withdrawn hepatotoxicity), gemifloxacin, delafloxacin (MRSA active). Black-box: tendinopathy / tendon rupture (esp. elderly + steroids), QT prolongation, peripheral neuropathy, CNS effects, hypoglycaemia, aortic aneurysm risk. 2018 FDA: use only when no alternative for uncomplicated UTI, sinusitis, bronchitis.
✘ A/B/C wrong: Different classes' targets.
28
Ciprofloxacin resistance mechanism: GPAT 2019
  • APoint mutations
  • BΞ²-lactamase production
  • CRibosomal methylation
  • DAltered cell wall

πŸ“˜ Explanation

βœ” Correct β€” A: Quinolone resistance complex. Target mutations are dominant mechanism; efflux contributes. Plasmid-mediated qnr proteins protect gyrase/topo IV; qepA & oqxAB are efflux plasmids. High level resistance in Enterobacteriaceae (esp. ESBL & CRE producers). India data: fluoroquinolone resistance ~ 60-80 % for typhoid, community E. coli β€” limits empirical use. Delafloxacin retains activity against some moderately resistant strains; nemonoxacin under development.
✘ B/C/D wrong: Other antibiotic class resistance mechanisms.
29
First-line drugs for drug-susceptible pulmonary TB (Category I, 6-month regimen): Most Probable
  • AStreptomycin + ethionamide
  • BIsoniazid + Rifampicin
  • CLevofloxacin + moxifloxacin
  • DBedaquiline monotherapy

πŸ“˜ Explanation

βœ” Correct β€” B: HRZE Γ— 2 months (intensive) + HR Γ— 4 months (continuation) = standard 6-month ATT. RNTCP (now NTEP) daily regimen (2017). Isoniazid: mycolic acid synthesis inhibitor (activated by KatG), ADR hepatotoxicity + peripheral neuropathy (give pyridoxine). Rifampicin: RNA polymerase inhibitor (rpoB), orange urine, CYP inducer. Pyrazinamide: active at acidic pH (bacterial activation), ADR hepatotoxicity + hyperuricaemia. Ethambutol: arabinosyl transferase inhibitor, ADR optic neuritis (colour vision ↓). 2022: 4-month regimen HPMZ (isoniazid-rifapentine-moxifloxacin-PZA) now recommended for non-severe DS-TB.
✘ A wrong: Streptomycin dropped from first-line.
✘ C wrong: Second-line.
✘ D wrong: Only for MDR/XDR-TB.
30
Isoniazid is a prodrug activated by: GPAT 2019
  • AHuman CYP3A4
  • BSpontaneous hydrolysis
  • CMycobacterial
  • DBacterial Ξ²-lactamase

πŸ“˜ Explanation

βœ” Correct β€” C: INH requires activation β€” katG encodes catalase-peroxidase that converts INH to isonicotinic acyl radical β†’ covalent INH-NAD adduct β†’ InhA inhibition. Resistance: katG loss-of-function mutation (INH resistance, often high level), InhA promoter mutation (low-level INH + cross-resistance to ethionamide). Pharmacogenetics: NAT2 acetylator status β€” slow acetylators (50 % Indians, Scandinavians) β†’ ↑ AUC β†’ ↑ neuropathy; fast acetylators β†’ ↓ AUC β†’ risk of low cure rate. Always coadminister pyridoxine (vit B6) 10-25 mg daily to prevent peripheral neuropathy.
✘ A/B/D wrong: Not the activation path.
31
Rifampicin mechanism: GPAT 2019
  • ABinds Ξ²-subunit of bacterial
  • BCell wall synthesis inhibitor
  • CRibosomal
  • DDHFR inhibitor

πŸ“˜ Explanation

βœ” Correct β€” A: Rifampicin (Rifampin in US) = rifamycin derivative (Streptomyces mediterranei, now Amycolatopsis mediterranei). Naphthalene-fused ansa macrocycle. ADR: orange-red discolouration of body fluids (urine, sweat, tears β€” contact lenses stain), hepatotoxicity, flu-like syndrome (intermittent dosing), thrombocytopenia. CYP INDUCER (3A4, 2C9, 2C19, 2D6, 1A2, UGT, P-gp) β†’ ↓ OCP (contraceptive failure), warfarin, cyclosporine, ART, methadone, midazolam. Rifabutin = weaker inducer, preferred with protease inhibitors. Rifapentine = long tΒ½ analogue used in HPMZ 4-month regimen & latent TB prophylaxis (3HP = isoniazid + rifapentine once weekly Γ— 12 weeks).
✘ B/C/D wrong: Other mechanisms.
32
Drug of choice for MDR-TB (MDR = resistant to isoniazid + rifampicin) per WHO 2022 guidance: GPAT 2019
  • AStreptomycin alone
  • BBPaL or BPaLM
  • CAmoxicillin-clavulanate
  • DMetronidazole

πŸ“˜ Explanation

βœ” Correct β€” B: Bedaquiline (Sirturo, 2012) β€” diarylquinoline; inhibits ATP synthase (mycobacterial F-ATP). Pretomanid (2019) β€” nitroimidazole, activated by Mtb Ddn. Linezolid β€” protein synthesis inhibitor. Moxifloxacin β€” fluoroquinolone. BPaL trial 90 % success in XDR-TB. BPaLM β€” first-line MDR-TB. Previously MDR regimen: Cm/Am + Lfx + Cs + Eto + Z (18-24 months, high toxicity). Delamanid = alternative nitroimidazole. Clofazimine, cycloserine, terizidone, linezolid, PAS = other 2nd-line. India's NTEP has adopted BPaLM.
✘ A/C/D wrong: Not MDR-TB regimens.
33
Amphotericin B is classified as: GPAT 2020
  • AAzole
  • BEchinocandin
  • CAllylamine
  • DPolyene antifungal

πŸ“˜ Explanation

βœ” Correct β€” D: Amphotericin B (Streptomyces nodosus 1955). Polyene macrolactone β€” hydrophilic polyol + hydrophobic polyene. Broad-spectrum antifungal β€” mould (Aspergillus) & yeast (Candida, Cryptococcus) & dimorphic (Histoplasma, Blastomyces, Coccidioides) & Mucormycosis (only drug with activity on many Mucorales). ADR: infusion reactions (chills, fever, hypotension β€” "shake & bake"), nephrotoxicity (tubular damage β€” pre-hydrate, monitor K+/Mg++), anaemia. Lipid formulations (L-AmB, ABLC, ABCD) β€” similar efficacy, ↓ toxicity. Nystatin (topical polyene) β€” oral candidiasis, vaginal. Natamycin β€” ophthalmic.
✘ A/B/C wrong: Different classes.
34
Azole antifungals mechanism: Most Probable
  • ABind cell wall
  • BInhibit fungal CYP51
  • CDestroy DNA
  • DInhibit 30S ribosome

πŸ“˜ Explanation

βœ” Correct β€” B: Imidazoles (topical mainly β€” clotrimazole, miconazole, econazole, ketoconazole β€” also PO historically but hepatotoxicity + adrenal). Triazoles (systemic): fluconazole (Candida except krusei/glabrata; oral, IV; BBB +), itraconazole (Aspergillus, endemic mycoses; oral capsule/solution), voriconazole (Aspergillus DOC; QT, visual disturbances, hepatotoxicity, SCC risk), posaconazole (broad incl. Mucor), isavuconazole (broad, tolerable, QT-shortener unlike others). Drug-drug interactions plentiful β€” all are CYP3A4 inhibitors (voriconazole + fluconazole also 2C9, 2C19). Resistance: ERG11 mutations, efflux (CDR, MDR pumps). Ketoconazole SYSTEMIC β€” also inhibits steroid synthesis (CYP17, CYP11) β€” used off-label for Cushing's.
✘ A/C/D wrong: Wrong targets.
35
Echinocandins (caspofungin, micafungin, anidulafungin, rezafungin): Most Probable
  • AInhibit Ξ²- -D-glucan
  • BBind ergosterol
  • CInhibit CYP51
  • DInhibit DNA synthesis

πŸ“˜ Explanation

βœ” Correct β€” A: Echinocandins = semi-synthetic cyclic lipopeptides. Unique fungal target (humans lack Ξ²-1,3-glucan synthase) = selective toxicity. Rezafungin (2023) β€” once-weekly dosing due to long tΒ½. Ibrexafungerp β€” first oral glucan synthase inhibitor (approved 2021 for vulvovaginal candidiasis). Resistance: fks1/fks2 hot spot mutations. No cross-resistance with azoles or AmB. DOC for candidaemia/invasive candidiasis (except CNS where fluconazole/AmB preferred due to CSF penetration).
✘ B wrong: Polyene mechanism.
✘ C wrong: Azole mechanism.
✘ D wrong: Flucytosine mechanism.
36
Griseofulvin mechanism: GPAT 2020
  • AErgosterol binder
  • BGlucan synthase inhibitor
  • CBinds fungal microtubule β†’ inhibits
  • DInhibits squalene epoxidase

πŸ“˜ Explanation

βœ” Correct β€” C: Griseofulvin (Penicillium griseofulvum 1939). Oral; absorbed best with fatty meal. Narrow spectrum β€” dermatophytes only (Trichophyton, Microsporum, Epidermophyton). Long duration: scalp ringworm (tinea capitis) 6-8 wks, onychomycosis 6-12 months. Largely replaced by: terbinafine (squalene epoxidase inhibitor β†’ squalene accumulates toxic; fungicidal; short duration 6 wks nails; oral/topical; hepatotoxic), itraconazole (pulse dosing for nails 400 mg/day 1 week/month Γ— 2-3 cycles). Topical: clotrimazole, ketoconazole, terbinafine, naftifine, butenafine, amorolfine, ciclopirox for superficial fungal.
✘ A/B/D wrong: Other targets.
37
Flucytosine (5-FC) mechanism: Most Probable
  • APolyene
  • BAzole
  • CEchinocandin
  • DFluorinated

πŸ“˜ Explanation

βœ” Correct β€” D: 5-FC β€” narrow-spectrum: Cryptococcus neoformans (cryptococcal meningitis in HIV β€” AmB + 5-FC induction phase), Candida. ADR: bone marrow suppression (from small amount of 5-FU formed in enterocytes by gut flora deaminase), hepatotoxicity, colitis. Dose-adjusted by TDM (peak < 100 Β΅g/mL). Oral bioavailability good. Monotherapy rapidly selects for resistance. Combined with fluconazole for cryptococcal meningitis in resource-limited settings where AmB unavailable.
✘ A/B/C wrong: Different classes.
38
Metronidazole is activated by: GPAT 2018
  • AOxidative environment
  • BReduction by anaerobic
  • CΞ²-lactamase
  • DCYP3A4

πŸ“˜ Explanation

βœ” Correct β€” B: Metronidazole β€” 5-nitroimidazole. Active against anaerobes (B. fragilis, Clostridia) + protozoa (Entamoeba, Giardia, Trichomonas). Uses: PID, intra-abdominal, pseudo-membranous colitis (oral for C. difficile β€” now vancomycin or fidaxomicin preferred), H. pylori (triple therapy), BV. ADR: metallic taste, nausea, disulfiram-like reaction (avoid alcohol 24 h), peripheral neuropathy (long use), rare neurotoxicity. CYP2C9 substrate, CYP3A4 inhibitor. Pregnancy category B (avoid 1st trimester). Tinidazole = longer tΒ½, similar spectrum. Nitazoxanide = broad anti-protozoal/anti-helminthic; active in Cryptosporidium, Giardia, H. pylori adjunct.
✘ A/C/D wrong: Not activation pathway.
39
Clindamycin mechanism: Most Probable
  • ABinds 50S ribosomal
  • BΞ²-lactam
  • CAminoglycoside
  • DDNA gyrase

πŸ“˜ Explanation

βœ” Correct β€” A: Clindamycin = lincosamide (chlorinated 7-deoxy derivative of lincomycin, Streptomyces lincolnensis). Excellent for aspiration pneumonia, lung abscess, necrotising fasciitis, MRSA soft-tissue (CA-MRSA often retains clinda sensitivity). Also inhibits toxin production in S. aureus/S. pyogenes (TSS β€” adjunct with antitoxin/IVIG). Uses: anaerobes, streptococci, staph (test D-zone for inducible clindamycin resistance = iMLSB phenotype), CA-MRSA, toxoplasmosis (with pyrimethamine), malaria (falciparum adjunct). Topical for acne. Resistance: erm methyltransferase (= MLSB, cross-resistance with macrolides + B streptogramin).
✘ B/C/D wrong: Different classes.
40
Voriconazole major ADR: GPAT 2020
  • ANephrotoxicity
  • BOtotoxicity
  • CVisual disturbances
  • DBone marrow suppression

πŸ“˜ Explanation

βœ” Correct β€” C: Voriconazole β€” 2nd-gen triazole; DOC for invasive aspergillosis. CYP2C19 genetic polymorphism important β€” poor metabolisers need lower dose (TDM recommended; target trough 1-5.5 Β΅g/mL). Many drug interactions (CYP3A4 substrate + inhibitor). Visual symptoms typically transient. Long-term use in immunocompromised β†’ skin SCC (avoid sun, regular dermatological screening). Isavuconazole = newer, tolerable, QT-shortening (not prolonging β€” unlike other azoles), broad-spectrum including Mucor.
✘ A/B/D wrong: Not signature.
41
Ethambutol ADR: GPAT 2019
  • AHyperuricaemia
  • BDose-dependent retrobulbar
  • COrange urine
  • DPeripheral neuropathy

πŸ“˜ Explanation

βœ” Correct β€” B: ATT ADR summary: Isoniazid β€” peripheral neuropathy (add pyridoxine), hepatotoxicity; Rifampicin β€” hepatotoxicity, orange body fluids, flu-like, CYP inducer; Pyrazinamide β€” hepatotoxicity, hyperuricaemia (avoid in gout), arthralgia; Ethambutol β€” optic neuritis, acidosis; Streptomycin β€” ototoxicity (vestibular), nephrotoxicity. Drug-induced hepatitis (DIH): if AST > 3Γ— ULN with symptoms, or > 5Γ— asymptomatic β†’ stop & re-challenge after recovery. Renal impairment: reduce Z + E doses; rifampicin + isoniazid safe.
✘ A wrong: Pyrazinamide.
✘ C wrong: Rifampicin.
✘ D wrong: Isoniazid.
42
Nitrofurantoin is used for: Most Probable
  • AUncomplicated lower UTI
  • BTB
  • CMeningitis
  • DPneumonia

πŸ“˜ Explanation

βœ” Correct β€” A: Nitrofurantoin β€” activated intracellularly by bacterial nitroreductase β†’ reactive intermediates damage DNA, ribosomes, cell wall. Concentrates in urine > 20Γ— serum β†’ effective cystitis agent. Dose: 100 mg BD Γ— 5 days. Preferred first-line due to minimal resistance & low collateral damage. ADR: acute pulmonary reactions (pneumonitis), chronic pulmonary fibrosis (long-term), peripheral neuropathy, hepatotoxicity, haemolysis in G6PD deficiency. CI: renal impairment (CrCl < 30 β€” inadequate urine levels + more toxicity), 3rd trimester (fetal haemolysis), neonates. Fosfomycin single 3 g dose β€” alternative for cystitis.
✘ B/C/D wrong: Not UTI indications.
43
Trimethoprim-sulphamethoxazole (cotrimoxazole) first choice for: GPAT 2020
  • ATB
  • BMeningococcus
  • CCholera
  • DPneumocystis

πŸ“˜ Explanation

βœ” Correct β€” D: PCP in HIV: cotrimoxazole TMP 15-20 mg/kg/day IV/PO for 21 days; prophylaxis at CD4 < 200. ARDS-like presentation in advanced immunosuppression β€” add steroids if PaOβ‚‚ < 70 mmHg. Pentamidine, atovaquone, primaquine-clindamycin = alternatives. Stenotrophomonas maltophilia β€” intrinsically resistant to carbapenems; cotrimoxazole is DOC. Whipple disease, brucella, listeria (alternative) also treated. Toxoplasmosis in immunocompromised: pyrimethamine + sulphadiazine + folinic acid (cotrimoxazole if SMX preferred). ADR: hyperkalaemia, rash, SJS, haemolysis in G6PD, renal impairment exaggerated creatinine.
✘ A/B/C wrong: Not DOC.
44
Terbinafine's mechanism: Practice Question
  • ACYP51 inhibitor
  • BAllylamine inhibitor of fungal
  • CΞ²-glucan synthase inhibitor
  • DPolyene

πŸ“˜ Explanation

βœ” Correct β€” B: Terbinafine (Lamisil) = allylamine. 250 mg OD Γ— 6 wks for fingernail, 12 wks for toenail onychomycosis. Topical 1 % cream for tinea corporis/cruris/pedis. ADR: hepatotoxicity (rare but idiosyncratic, check LFTs), taste disturbance, neutropenia, SJS/TEN, lupus flare, depression. CYP2D6 inhibitor β†’ care with antidepressants, Ξ²-blockers. Naftifine, butenafine β€” related topicals. Tolnaftate (OTC topical) β€” similar mechanism.
✘ A/C/D wrong: Other antifungal classes.
UNIT III
Antivirals Β· Antimalarials Β· Antiprotozoals (Q45 – Q62)
45
Acyclovir is: GPAT 2019
  • AAcyclic guanosine analogue
  • BCytosine analogue
  • CThymidine analogue
  • DNNRTI

πŸ“˜ Explanation

βœ” Correct β€” A: Acyclovir (Zovirax) β€” first ACV-TK activation step unique to infected cells β†’ selectivity. Uses: HSV-1/2 (genital, orolabial, encephalitis, keratitis), VZV (chickenpox, shingles). Poor oral bioavailability (20%) β†’ prodrugs valacyclovir (55%), famciclovir (β†’ penciclovir); ganciclovir & valganciclovir for CMV (broader DNA pol inhibition; myelotoxic). Resistance: TK mutation β†’ switch to foscarnet (PPi analogue, no activation) or cidofovir. ADR: nephrotoxicity (crystalluria β€” hydrate), neurotoxicity (myoclonus, encephalopathy esp. elderly/renal).
✘ B/C/D wrong: Different.
46
Zidovudine (AZT) class: GPAT 2019
  • AProtease inhibitor
  • BIntegrase inhibitor
  • CNucleoside Reverse
  • DCCR5 antagonist

πŸ“˜ Explanation

βœ” Correct β€” C: NRTIs: zidovudine (AZT, ZDV), lamivudine (3TC), emtricitabine (FTC), tenofovir (TDF/TAF), abacavir (ABC), didanosine (ddI β€” obsolete), stavudine (d4T β€” obsolete). ART regimens: 2 NRTIs (TDF/TAF + FTC/3TC) + third agent (integrase inhibitor preferred β€” dolutegravir, bictegravir, raltegravir). NNRTIs (non-nucleoside RT inhibitors β€” efavirenz, rilpivirine, doravirine); PIs (ritonavir-boosted atazanavir/darunavir); entry inhibitors (maraviroc CCR5, enfuvirtide fusion); integrase strand transfer inhibitors (INSTIs). Long-acting cabotegravir + rilpivirine injection every 2 months.
✘ A/B/D wrong: Other classes.
47
Oseltamivir class: Most Probable
  • AM2 ion-channel blocker
  • BNRTI
  • CNNRTI
  • DNeuraminidase

πŸ“˜ Explanation

βœ” Correct β€” D: Neuraminidase = viral surface enzyme that cleaves sialic acid from host cells β†’ releases new virion. Inhibitors: oseltamivir (Tamiflu, oral prodrug β†’ oseltamivir carboxylate), zanamivir (Relenza, inhaled), peramivir (IV), laninamivir (inhaled, Japan). M2 inhibitors (amantadine, rimantadine) β€” withdrawn for influenza due to resistance (now used in Parkinson's). Baloxavir marboxil (Xofluza, 2018) β€” first-in-class PA endonuclease inhibitor for influenza; single-dose oral. Oseltamivir: rationale in epidemics/pandemics (swine flu H1N1 2009, COVID-flu coinfections); modest benefit in uncomplicated flu but reduces complications in high-risk.
✘ A wrong: Amantadine class (withdrawn).
✘ B/C wrong: HIV classes.
48
Remdesivir mechanism: Most Probable
  • AProtease inhibitor
  • BAdenosine nucleotide
  • CNeuraminidase inhibitor
  • DM2 blocker

πŸ“˜ Explanation

βœ” Correct β€” B: Remdesivir (Veklury) β€” broad-spectrum RdRp inhibitor originally developed for Ebola; approved for SARS-CoV-2 (2020). IV only, 5 days (or 10 for ventilated). Evidence: shortens time to recovery (ACTT-1 trial), mixed mortality benefit (Solidarity showed no mortality ↓). Works best early + high-risk outpatients. Other COVID drugs: nirmatrelvir/ritonavir (Paxlovid β€” SARS-CoV-2 main protease inhibitor, oral 5 days early; many drug interactions via CYP3A4); molnupiravir (oral mutagenic ribonucleoside β†’ error catastrophe; teratogenic CI pregnancy); ensitrelvir (Xocova, Japan). Monoclonal antibodies mostly obsolete due to variants.
✘ A/C/D wrong: Different antiviral classes.
49
Chloroquine resistance mechanism in Plasmodium falciparum: GPAT 2020
  • AΞ²-lactamase
  • BEfflux of chloroquine from parasite food vacuole β€” encoded by pfcrt gene mutation (K76T primary marker) + pfmdr1
  • CEfflux via pfcrt gene mutation
  • DTarget amplification

πŸ“˜ Explanation

βœ” Correct β€” C: Chloroquine accumulates in parasite food vacuole (acidic pH) by ion trapping β†’ binds ferriprotoporphyrin IX (haem β€” toxic by-product of haemoglobin digestion) β†’ prevents haemozoin (hemozoin) polymerisation β†’ parasite toxicity. Resistance (PfCRT K76T mutation) β†’ accelerated efflux of protonated chloroquine out of vacuole. CQ now obsolete for P. falciparum in almost all endemic regions (widespread resistance since 1990s). Still effective for P. vivax (some resistance emerging) + P. ovale + P. malariae. Hydroxychloroquine β€” similar to CQ; also used in SLE, RA (autoimmune).
✘ A/D wrong: Other mechanisms.
50
Primaquine is used for: GPAT 2020
  • ARadical cure of vivax malaria
  • BOnly erythrocytic stage
  • CFungal infections
  • DTB

πŸ“˜ Explanation

βœ” Correct β€” A: Primaquine β€” 8-aminoquinoline. After blood stages cleared by chloroquine/artemisinin β†’ primaquine 0.25-0.5 mg/kg/day Γ— 14 days for radical cure (prevents relapse from liver hypnozoites in P. vivax/ovale). Tafenoquine (Krintafel) β€” single-dose 300 mg alternative for radical cure, approved 2018, but same G6PD concern. Severe haemolysis in G6PD-deficient patients (5-10% in many endemic areas) β€” routinely test. Methaemoglobinaemia. CI in pregnancy + infancy (fetal G6PD status unknown). Gametocyte-killing reduces transmission β€” public health benefit.
✘ B wrong: Schizonticides (chloroquine, artemisinin).
✘ C wrong: Antifungals.
✘ D wrong: Anti-TB.
51
Artemisinin-based combination therapy (ACT) β€” first-line for P. falciparum malaria: GPAT 2020
  • AChloroquine alone
  • BExamples
  • CMefloquine alone
  • DPrimaquine alone

πŸ“˜ Explanation

βœ” Correct β€” B: Artemisinins β€” rapid parasite clearance but short half-life β†’ must combine with longer-acting partner to prevent resistance. WHO recommends 5 ACTs for uncomplicated malaria. Severe falciparum malaria: IV/IM artesunate Γ— 24 h (minimum 3 doses), then complete with oral ACT. Monotherapy with artemisinins is prohibited by WHO. India NVBDCP first-line: AL (artemether-lumefantrine) in North-East, AS+SP elsewhere. Resistance to artemisinins emerged in Greater Mekong (Cambodia, Thailand, Myanmar) β€” kelch13 (K13) propeller mutations; now spreading to Africa (Rwanda, Uganda). Triple-ACT (e.g., DHA-PPQ + mefloquine) under study.
✘ A/C/D wrong: Monotherapies not recommended for falciparum.
52
Metronidazole is DOC for: GPAT 2018
  • AMalaria
  • BLeishmaniasis
  • CTrypanosomiasis
  • DIntestinal & hepatic

πŸ“˜ Explanation

βœ” Correct β€” D: Amoebiasis therapy: (1) Metronidazole 800 mg TDS Γ— 5-10 days for invasive disease (intestinal + hepatic); (2) follow with a LUMINAL agent (paromomycin, iodoquinol, diloxanide furoate) to eradicate intraluminal cysts (metronidazole does not reach the colonic lumen well). Tinidazole = longer tΒ½ (14 h), once daily dosing alternative. Nitazoxanide β€” for Cryptosporidium, also Giardia. ADR metronidazole: metallic taste, disulfiram-like (avoid alcohol), peripheral neuropathy (prolonged use), neurotoxicity. Category B pregnancy (avoid 1st trimester).
✘ A/B/C wrong: Not primary indications.
53
Sofosbuvir mechanism: Most Probable
  • ANS5B polymerase inhibitor
  • BProtease inhibitor
  • CIntegrase inhibitor
  • DCCR5 antagonist

πŸ“˜ Explanation

βœ” Correct β€” A: DAA era revolutionised HCV β€” cure rates > 95 % with 8-12 week oral regimens (no interferon/ribavirin). Classes: NS3/4A protease inhibitors (-previr suffix β€” glecaprevir, voxilaprevir, grazoprevir); NS5A inhibitors (-asvir β€” ledipasvir, velpatasvir, elbasvir, pibrentasvir); NS5B polymerase inhibitors (-buvir β€” sofosbuvir nucleotide, dasabuvir non-nucleoside). Pan-genotypic regimens: sofosbuvir/velpatasvir (Epclusa), glecaprevir/pibrentasvir (Mavyret). WHO 2030 goal: HCV elimination β€” India has generic DAA production enabling cost < $100 per course.
✘ B/C/D wrong: HIV drug classes.
54
Liposomal amphotericin B is DOC for: GPAT 2020
  • AHIV
  • BVisceral leishmaniasis
  • CMalaria
  • DTB

πŸ“˜ Explanation

βœ” Correct β€” B: Kala-azar (Leishmania donovani in Indian subcontinent). Previous first-line: sodium stibogluconate (pentavalent antimony β€” now obsolete in India due to resistance in Bihar > 60 %). Current first-line: single-dose liposomal AmB 10 mg/kg (99 % cure; WHO-recommended); alternative miltefosine (first oral anti-leishmanial, 100 mg Γ— 28 days, teratogenic); paromomycin injection 15 mg/kg Γ— 21 days; combinations for XDR / PKDL. HIV-VL coinfection requires combination + ART. India's Kala-azar Elimination Programme targets < 1 case/10,000 at sub-district level.
✘ A/C/D wrong: Different diseases.
55
Miltefosine mechanism: Most Probable
  • AInhibits DNA
  • BKills by osmotic disruption
  • CAlkylphosphocholine that disrupts
  • DFolate antagonist

πŸ“˜ Explanation

βœ” Correct β€” C: Miltefosine (hexadecylphosphocholine) β€” originally developed as anticancer agent; approved 2002 for VL. Active against cutaneous leishmaniasis (L. braziliensis), mucocutaneous, visceral, free-living amoeba (Acanthamoeba, Naegleria, Balamuthia β€” last-resort in PAM). ADR: GI (common), hepatotoxic, nephrotoxic, teratogenic. Long tΒ½ (~ 150 h) means contraception for 3 months after. Resistance: alterations in P-type ATPase, CDR1 efflux.
✘ A/B/D wrong: Not the mechanism.
56
Pentamidine is used for: Most Probable
  • AAfrican trypanosomiasis
  • BTB
  • CHIV
  • DInfluenza

πŸ“˜ Explanation

βœ” Correct β€” A: Pentamidine β€” aromatic diamidine; intracellular binding to DNA (kinetoplast), inhibits multiple parasite enzymes. IM / IV / inhaled (for PCP prophylaxis). Severe ADR: severe hypotension (IV infusion), hypoglycaemia + ketoacidosis + insulin-dependent diabetes, pancreatitis, nephrotoxicity, QT prolongation, arrhythmias. For T. brucei gambiense stage 2 (CNS) β€” eflornithine (DFMO) or nifurtimox-eflornithine combination therapy (NECT). T. brucei rhodesiense (East African) β€” suramin (stage 1), melarsoprol (stage 2; very toxic with post-treatment reactive encephalopathy 5-10 %). Fexinidazole (2018) β€” first oral drug for both stages.
✘ B/C/D wrong: Not the indications.
57
Nifurtimox + benznidazole used for: Most Probable
  • AMalaria
  • BKala-azar
  • CGiardiasis
  • DAmerican trypanosomiasis

πŸ“˜ Explanation

βœ” Correct β€” D: Chagas disease β€” Trypanosoma cruzi, transmitted by reduviid bug ("kissing bug") in Latin America. Acute phase β€” myocarditis, meningoencephalitis. Chronic β€” "megasyndromes" (megacolon, megaoesophagus, cardiomyopathy β†’ heart failure). Benznidazole (first-line, 60 days) + nifurtimox (alternative). Both are nitro-heterocycles activated by parasite nitroreductase. ADR: GI, peripheral neuropathy, rash, bone marrow suppression. WHO Chagas elimination effort. Fexinidazole (approved 2018) also for Chagas in some regulatory approvals.
✘ A/B/C wrong: Other diseases.
58
Mefloquine is used for: GPAT 2020
  • AAmoebiasis
  • BMalaria chemoprophylaxis
  • CLeishmaniasis
  • DTrypanosomiasis

πŸ“˜ Explanation

βœ” Correct β€” B: Mefloquine (Lariam) β€” arylaminoalcohol; long tΒ½ (3 weeks); weekly dosing for prophylaxis + 3-dose treatment. ADR: neuropsychiatric (vivid dreams, anxiety, depression, psychosis β€” FDA black box 2013); cardiotoxicity (QT). CI: history of seizures, depression, psychosis; 1st-trimester pregnancy (2nd-3rd OK). Atovaquone-proguanil (Malarone) = daily alternative with better tolerability but shorter duration. Doxycycline β€” cheaper daily option with photosensitivity. Tafenoquine (ArakodaΓ”) β€” weekly prophylaxis like primaquine but single-dose.
✘ A/C/D wrong: Different indications.
59
Oseltamivir dose for adult influenza treatment (5 days): Most Probable
  • A75 mg BD oral Γ— 5 days
  • B500 mg single dose
  • C10 mg IV
  • D1 g TID

πŸ“˜ Explanation

βœ” Correct β€” A: Oseltamivir β€” prodrug oseltamivir phosphate β†’ oseltamivir carboxylate (active). Adult 75 mg BD Γ— 5 days treatment; 75 mg OD Γ— 7-10 days prophylaxis. Paediatric dose by weight. Severe influenza may need dose increase + duration extension. Renal dose adjustment if CrCl < 30. ADR: nausea & vomiting (take with food), transient neuropsychiatric events in children (Japan reports). Rising resistance β€” H275Y mutation in H1N1pdm09 β†’ oseltamivir-resistant. Baloxavir 40-80 mg single dose alternative.
✘ B/C/D wrong: Wrong dose/route.
60
Pyrimethamine is used for toxoplasmosis β€” always given with: Most Probable
  • AVitamin B12
  • BLeucovorin
  • CPyridoxine
  • DVitamin C

πŸ“˜ Explanation

βœ” Correct β€” B: Pyrimethamine β€” 2,4-diaminopyrimidine; DHFR inhibitor selective for parasite DHFR (~ 1000Γ— selectivity). Uses: toxoplasmosis (with sulphadiazine, "Toxo regimen"); P. falciparum malaria (with sulphadoxine as Fansidar; now obsolete for prophylaxis due to resistance; IPT-p for pregnant women in Africa); Pneumocystis (alternative to cotrimoxazole). Folinic acid bypasses DHFR block in host (parasite cannot use folic acid from outside β†’ selective). Price controversy β€” Turing Pharmaceuticals raised US price from $13.50 to $750/pill (2015, Martin Shkreli).
✘ A/C/D wrong: Other vitamins.
61
Praziquantel is antihelmintic β€” active against: Most Probable
  • AMalaria
  • BAmoebiasis
  • CSchistosomiasis
  • DOnly nematodes

πŸ“˜ Explanation

βœ” Correct β€” C: Praziquantel β€” drug of choice for all forms of schistosomiasis (S. mansoni, haematobium, japonicum, intercalatum, mekongi), taeniasis (T. saginata, solium), hymenolepiasis, diphyllobothriasis. Also used in CNS cysticercosis (with dexamethasone + albendazole β€” 15 mg/kg Γ— 8-30 days). Liver flukes (Opisthorchis, Clonorchis) responsive. Dose 20-25 mg/kg q 4 h Γ— 3 doses. ADR: abdominal cramps, dizziness, urticaria (dying parasite reaction). Larval cestode infestations (hydatid disease β€” Echinococcus) β€” albendazole primary.
✘ A/B/D wrong: Not the spectrum.
62
Ivermectin is used for: Practice Question
  • AOnchocerciasis
  • BMalaria
  • CHIV
  • DCancer

πŸ“˜ Explanation

βœ” Correct β€” A: Ivermectin (Mectizan) β€” macrocyclic lactone from Streptomyces avermitilis (Campbell & Ōmura Nobel 2015). Binds parasite Glu-Cl channels β†’ hyperpolarisation/paralysis (mammals lack these; GABA-A less affected below clinical doses). P-gp protects mammalian BBB from entry β€” hence safety. Mass drug administration programmes for river blindness (Onchocerciasis) in Africa & Americas (donated by Merck since 1987 = "Mectizan Donation Program"); elephantiasis (lymphatic filariasis) under WHO GPELF. COVID-19 controversy β€” no proven benefit in RCTs (WHO, FDA, EMA discouraged use).
✘ B/C/D wrong: Not standard indications.
UNIT IV
Anthelmintics Β· Urinary Antiseptics Β· Anti-leprotics (Q63 – Q72)
63
Albendazole mechanism: Most Probable
  • ACa²⁺ channel blocker
  • BBenzimidazole
  • CGABA-A agonist
  • DFolate antagonist

πŸ“˜ Explanation

βœ” Correct β€” B: Albendazole (Zentel) β€” single 400 mg for Ascaris, hookworm, Enterobius (pinworm β€” repeat 2 weeks); multiple doses for strongyloidiasis, cutaneous larva migrans, trichinellosis, echinococcosis (hydatid cyst 10-15 mg/kg Γ— 1-6 months). Also covers Taenia, Giardia, microsporidia, neurocysticercosis (with praziquantel + steroids). Metabolised to active albendazole sulphoxide. Food (fatty) ↑ absorption. Mebendazole = older benzimidazole, similar spectrum. ADR: hepatotoxic with long-term use, marrow suppression. Teratogenic (avoid 1st trimester).
✘ A/C/D wrong: Wrong mechanisms.
64
Diethylcarbamazine (DEC) is used for: Most Probable
  • ALymphatic filariasis
  • BMalaria
  • CAmoebiasis
  • DTB

πŸ“˜ Explanation

βœ” Correct β€” A: DEC = piperazine derivative; microfilaricidal + partially adulticidal. India's "National Filaria Elimination Programme" β€” annual MDA with DEC + albendazole in endemic districts. Dose: 6 mg/kg Γ— 12 days for individual, or 400 mg single dose in MDA. CI: onchocerciasis (causes Mazzotti-like severe reaction) + co-infection with Loa loa (risk of encephalopathy). Triple therapy IDA (ivermectin + DEC + albendazole) β€” new WHO-endorsed MDA strategy for accelerated elimination.
✘ B/C/D wrong: Other diseases.
65
Pyrantel pamoate mechanism: Most Probable
  • AΞ²-tubulin binder
  • BFolate antagonist
  • CDepolarising neuromuscular blocker
  • DDNA polymerase inhibitor

πŸ“˜ Explanation

βœ” Correct β€” C: Pyrantel β€” OTC in many countries; single dose 10-11 mg/kg. Covers Ascaris lumbricoides, Enterobius vermicularis (pinworm), hookworms. Not effective against whipworm (Trichuris). Safe profile. Levamisole (another nAChR agonist; historically for Ascaris, now rarely β€” immunomodulator in cocaine adulteration). Pyrantel contrast: piperazine β€” GABA agonist β†’ flaccid paralysis (obsolete due to toxicity). Tapeworms respond to niclosamide (oxidative phosphorylation uncoupler β€” tapeworm-specific) or praziquantel.
✘ A/B/D wrong: Different mechanisms.
66
First-line anti-leprosy regimen (WHO MDT, multi-drug therapy): Most Probable
  • AMultibacillary leprosy
  • BIsoniazid alone
  • CStreptomycin monotherapy
  • DPenicillin

πŸ“˜ Explanation

βœ” Correct β€” A: India's National Leprosy Eradication Programme (NLEP) provides MDT blister packs free. Dapsone = DHPS inhibitor (similar to sulphonamides); ADR = haemolysis in G6PD, methaemoglobinaemia, sulphone syndrome, agranulocytosis. Clofazimine = red-orange pigmentation (reversible), GI, crystal deposits in liver/lymph nodes. Rifampicin same as anti-TB. 2018 WHO recommended single-dose rifampicin + moxifloxacin + minocycline as post-exposure prophylaxis. Second-line drugs: minocycline, clarithromycin, ofloxacin, moxifloxacin.
✘ B/C/D wrong: Monotherapies not used.
67
Dapsone (4,4'-diaminodiphenylsulphone) mechanism: Most Probable
  • ACell wall
  • BInhibits
  • CDNA gyrase
  • DRibosomal 50S

πŸ“˜ Explanation

βœ” Correct β€” B: Dapsone β€” sulphone; same site as sulphonamides. Uses: leprosy, PCP prophylaxis, dermatitis herpetiformis (anti-inflammatory action), acne, vasculitis. Also used for insect-bite reactions with toxic necrosis (brown recluse spider β€” though evidence weak). ADR: haemolytic anaemia (especially in G6PD deficiency β€” test first!), methaemoglobinaemia (treat with methylene blue), agranulocytosis, dapsone hypersensitivity syndrome (DRESS), motor neuropathy (long-term high dose), skin pigmentation. NAT2 polymorphism β€” slow acetylators accumulate more β†’ ↑ ADR.
✘ A/C/D wrong: Wrong targets.
68
Clofazimine's unique ADR: Most Probable
  • AOtotoxicity
  • BNephrotoxicity
  • CNeuropathy
  • DReddish-brown to black

πŸ“˜ Explanation

βœ” Correct β€” D: Clofazimine β€” riminophenazine; binds mycobacterial DNA + generates reactive oxygen species. Highly lipophilic β†’ accumulates in adipose & skin & macrophages β†’ pigmentation. Phase II trial showed QT prolongation in MDR-TB. Also has anti-inflammatory properties β€” useful in ENL (Erythema Nodosum Leprosum) type 2 lepra reaction. Alternative leprosy drugs: ofloxacin, minocycline, clarithromycin. For ENL reactions: thalidomide (WHO recommended β€” CI pregnancy), prednisolone, pentoxifylline.
✘ A/B/C wrong: Not the characteristic ADR.
69
Methenamine is a urinary antiseptic that releases: Most Probable
  • AChlorine
  • BIodine
  • CFormaldehyde
  • DMercury

πŸ“˜ Explanation

βœ” Correct β€” C: Methenamine (hexamine) β€” hexamethylenetetramine; in acidic urine decomposes to formaldehyde + NH4. Used for long-term UTI prophylaxis (not treatment). Must co-administer acidifier (mandelic acid = methenamine mandelate; hippuric acid = methenamine hippurate). Limited efficacy against urease-producing organisms (Proteus, Providencia) that alkalinise urine. Alternatives for UTI prophylaxis: low-dose nitrofurantoin, trimethoprim, cranberry products (modest evidence), D-mannose, vaccine (Uro-Vaxom), topical vaginal estrogen (postmenopausal).
✘ A/B/D wrong: Wrong chemistry.
70
Nalidixic acid (1st gen quinolone) primary use: GPAT 2019
  • AUncomplicated UTI
  • BMeningitis
  • CEndocarditis
  • DTB

πŸ“˜ Explanation

βœ” Correct β€” A: Nalidixic acid (1962) = founder of quinolone class; narrow G⁻ (E. coli, Proteus, etc.); used for UTI & bacillary dysentery historically. Modern era: fluoroquinolones (ciprofloxacin, levofloxacin) have superseded nalidixic acid; nalidixic acid sensitivity used in labs as surrogate for emerging fluoroquinolone non-susceptibility in Salmonella. Pipemidic acid, pefloxacin = 2nd gen; cinoxacin intermediate. SAR of quinolone: C3 COOH + C4 ketone essential; C6 F ↑ gyrase binding; C7 piperazine/pyrrolidine ↑ spectrum; C8 methoxy ↓ phototoxicity.
✘ B/C/D wrong: Not adequate for these.
71
Fosfomycin mechanism & use: Most Probable
  • AΞ²-lactam
  • BRibosomal 30S binder
  • CFolate antagonist
  • DPhosphoenolpyruvate analogue

πŸ“˜ Explanation

βœ” Correct β€” D: Fosfomycin (Streptomyces fradiae 1969) β€” small MW, broad spectrum including some ESBL/CRE strains. Oral trometamol salt concentrates in urine; single dose for uncomplicated cystitis. IV disodium salt for severe infection. Bactericidal. Resistance: MurA mutation, uhpT/glpT transporter loss (↓ uptake), fosA/fosB enzymes (glutathione/cysteine transferases β€” inactivate). Safety: safe in pregnancy. Synergistic with Ξ²-lactams, carbapenems β€” used in combinations for MDR UTI.
✘ A/B/C wrong: Wrong mechanisms.
72
Thalidomide in leprosy: Practice Question
  • AFirst-line anti-leprotic
  • BDrug of choice for ENL
  • CAntimycobacterial
  • DSteroid replacement

πŸ“˜ Explanation

βœ” Correct β€” B: Thalidomide (1950s β€” sedative/antiemetic for pregnancy β†’ phocomelia disaster β†’ withdrawn 1961). Rediscovered for ENL (1965), then multiple myeloma + MGUS, cutaneous lupus, Crohn's fistulae, Kaposi sarcoma. Mechanism: binds cereblon (CRBN β†’ part of CRL4 E3 ubiquitin ligase); degrades IKZF1/3 transcription factors β†’ immunomodulation; inhibits TNF-Ξ±, angiogenesis (VEGF, FGF). Derivatives: lenalidomide (Revlimid), pomalidomide (Pomalyst) β€” more potent, less teratogenic. STEPS/REMS programme mandatory: pregnancy test every 4 weeks, 2 contraception methods, physician + pharmacy certification.
✘ A/C/D wrong: Not primary use.
UNIT V
Anti-neoplastic Agents β€” Alkylating, Antimetabolites, Antibiotics, Plant Products, Targeted, Immunomodulators (Q73 – Q90)
73
Cyclophosphamide is a: GPAT 2020
  • ANitrogen mustard-type
  • BAntimetabolite
  • CPlant alkaloid
  • DTopoisomerase inhibitor

πŸ“˜ Explanation

βœ” Correct β€” A: Cyclophosphamide uses: lymphomas, leukaemias, myeloma, breast cancer, SLE, RA (off-label), vasculitis, nephrotic syndrome. Oral + IV. ADR: myelosuppression, haemorrhagic cystitis (due to acrolein β€” prevented by MESNA (2-mercaptoethanesulphonate sodium) binding acrolein + hydration), alopecia, nausea, teratogenic, secondary malignancy (AML, bladder TCC), ↑ infection, infertility. Ifosfamide = isomer; more CNS toxicity (encephalopathy β€” methylene blue reversal). Nitrogen mustards: mechlorethamine, chlorambucil, melphalan. Other alkylators: busulfan (myeloablative pre-BMT), thiotepa, dacarbazine, temozolomide, procarbazine, carmustine (BCNU)/lomustine (CCNU) nitrosoureas for CNS tumours.
✘ B/C/D wrong: Different classes.
74
Cisplatin mechanism: Most Probable
  • AMicrotubule stabilisation
  • BAntimetabolite
  • CPlatinum compound that forms
  • DTopoisomerase inhibitor

πŸ“˜ Explanation

βœ” Correct β€” C: Cisplatin = cis-diamminedichloroplatinum(II). Discovered serendipitously by Rosenberg 1965. Uses: testicular (curative regimen with bleomycin + etoposide = BEP), ovarian, bladder, cervical, head & neck, small cell lung, osteosarcoma. ADR: nephrotoxicity (always hydrate; amifostine protective), ototoxicity (high-frequency hearing loss), peripheral neuropathy, severe nausea/vomiting (NK1 + 5-HT3 + dexa + olanzapine CINV regimen mandatory). Carboplatin = less toxic analogue; dose by AUC (Calvert formula using GFR). Oxaliplatin = colorectal (FOLFOX regimen); cold-induced neuropathy (dysesthesia).
✘ A/B/D wrong: Other mechanisms.
75
Methotrexate mechanism: GPAT 2019
  • AAlkylator
  • BFolate analogue β†’ potent
  • CPlatinum compound
  • DMicrotubule binder

πŸ“˜ Explanation

βœ” Correct β€” B: Methotrexate (MTX) β€” used in ALL (CNS prophylaxis intrathecal), osteosarcoma, choriocarcinoma, lymphomas, RA (low dose weekly + folic acid), psoriasis, ectopic pregnancy (single dose). ADR: myelosuppression, stomatitis, hepatotoxicity (long-term fibrosis β€” monitor), pulmonary fibrosis, nephrotoxicity (crystalluria in high dose), mucositis. Interactions: NSAIDs, sulphonamides, PPI ↑ MTX levels. Pregnancy CI (abortifacient, teratogenic). Other antimetabolites: 6-MP, 6-thioguanine (purine analogues β€” ALL maintenance; TPMT pharmacogenetics), pemetrexed (lung cancer, mesothelioma β€” multitargeted antifolate), fluorouracil (5-FU β€” colorectal), capecitabine (oral 5-FU prodrug), cytarabine (ara-C β€” AML), gemcitabine (pancreas, NSCLC), cladribine, fludarabine, clofarabine.
✘ A/C/D wrong: Different classes.
76
5-fluorouracil (5-FU) mechanism: GPAT 2019
  • AFluorinated pyrimidine
  • BAlkylator
  • CMicrotubule binder
  • DTopoisomerase inhibitor

πŸ“˜ Explanation

βœ” Correct β€” A: 5-FU cornerstone in colorectal, breast, head & neck, gastric, pancreatic cancer. Typically continuous infusion to maximise S-phase exposure (vs bolus). Combined with leucovorin (5-formyl-THF) which stabilises ternary complex β†’ ↑ efficacy. Capecitabine (Xeloda) = oral 5-FU prodrug activated by thymidine phosphorylase (higher in tumour). DPYD pharmacogenetics (deficient alleles cause severe toxicity β€” monitor / dose adjust). ADR: diarrhoea, mucositis, hand-foot syndrome (palmar-plantar erythrodysaesthesia, especially capecitabine), neutropenia, cardiotoxicity (coronary vasospasm, rare with continuous infusion).
✘ B/C/D wrong: Different mechanisms.
77
Doxorubicin mechanism: Most Probable
  • AAlkylator
  • BAntimetabolite
  • CPlant alkaloid
  • DAnthracycline antibiotic

πŸ“˜ Explanation

βœ” Correct β€” D: Anthracyclines: daunorubicin, doxorubicin, idarubicin, epirubicin. Used in AML/ALL (daunorubicin, idarubicin), lymphomas, breast cancer, sarcoma, Hodgkin's (AVBD β€” adriamycin/doxo-VBD). Signature toxicity = cardiotoxicity (acute reversible; chronic dose-dependent irreversible cardiomyopathy β†’ CHF; cumulative dose limit 450-550 mg/mΒ² doxorubicin). Mechanism: topo II + iron-mediated ROS. Dexrazoxane = iron chelator β†’ cardioprotective. Pegylated liposomal doxorubicin (Doxil) β€” reduced cardiotoxicity but causes hand-foot syndrome. Mitoxantrone (not anthracycline, but similar; for MS, prostate cancer, blue discolouration). Bleomycin = non-anthracycline antitumour antibiotic causing pulmonary fibrosis (cumulative > 400 units, oxygen exposure aggravates).
✘ A/B/C wrong: Different classes.
78
Paclitaxel class & mechanism: GPAT 2020
  • AAlkylator
  • BAntimetabolite
  • CTaxane
  • DAnthracycline

πŸ“˜ Explanation

βœ” Correct β€” C: Paclitaxel (Taxol) β€” uses: ovarian, breast, NSCLC, Kaposi sarcoma. Docetaxel (Taxotere) β€” breast, NSCLC, prostate. Cabazitaxel β€” castration-resistant prostate after docetaxel. ADR: neutropenia, peripheral neuropathy (often dose-limiting), alopecia, hypersensitivity (Cremophor EL vehicle β€” premedicate with steroid + H1 + H2), myalgia. Nab-paclitaxel (Abraxane) β€” albumin-bound, no Cremophor, no premedication, better tolerated. Vinca alkaloids (from Catharanthus) = MT-DEstabilisers (opposite β€” prevent assembly): vincristine (ALL, lymphoma β€” neuropathic), vinblastine (testicular, lymphoma β€” more myelosuppressive), vinorelbine (NSCLC, breast), vindesine, vinflunine.
✘ A/B/D wrong: Different classes.
79
Imatinib mechanism: GPAT 2021
  • ADNA intercalator
  • BFirst-in-class
  • CMicrotubule inhibitor
  • DAlkylator

πŸ“˜ Explanation

βœ” Correct β€” B: Imatinib (Gleevec/Glivec) β€” 2001 approval marks "targeted therapy" era. 2nd gen TKIs (for resistance, T315I mutation exception): dasatinib, nilotinib, bosutinib; 3rd gen: ponatinib (covers T315I). TKIs for other targets: EGFR β€” erlotinib, gefitinib, afatinib, osimertinib (NSCLC); VEGFR β€” sunitinib, sorafenib, pazopanib, lenvatinib; ALK β€” crizotinib, alectinib, lorlatinib; BRAF β€” vemurafenib, dabrafenib + MEK (trametinib, cobimetinib) combinations; JAK β€” ruxolitinib, tofacitinib; BTK β€” ibrutinib, acalabrutinib; CDK4/6 β€” palbociclib, ribociclib, abemaciclib (breast); PARP β€” olaparib, rucaparib (BRCA1/2 ovarian, breast, prostate).
✘ A/C/D wrong: Not imatinib mechanism.
80
Trastuzumab target: GPAT 2021
  • AHER2 receptor
  • BEGFR
  • CVEGF
  • DCD20

πŸ“˜ Explanation

βœ” Correct β€” A: Trastuzumab (Herceptin). ADR: cardiotoxicity (monitor LVEF; avoid concomitant anthracycline β€” reserve for sequential), infusion reactions. HER2 combinations: pertuzumab + trastuzumab + docetaxel. Biosimilars widely available in India (trastuzumab). Targets of other mAbs: EGFR β€” cetuximab, panitumumab (KRAS wild-type colorectal); VEGF β€” bevacizumab (Avastin, colorectal, ovarian, glioblastoma); CD20 β€” rituximab (lymphoma, RA, ITP, vasculitis); PD-1 β€” nivolumab, pembrolizumab; PD-L1 β€” atezolizumab, durvalumab, avelumab; CTLA-4 β€” ipilimumab; CD38 β€” daratumumab (MM); Bcl-2 β€” venetoclax (small molecule β€” CLL, AML).
✘ B/C/D wrong: Other mAb targets.
81
Rituximab target: GPAT 2021
  • ACD3
  • BCD19
  • CCD20
  • DHER2

πŸ“˜ Explanation

βœ” Correct β€” C: Rituximab (MabThera, Rituxan) β€” first approved mAb for cancer (1997). Chimeric (mouse-human). ADR: infusion reactions (slow first infusion + premedication), reactivation of Hepatitis B (screen before), PML (JC virus), late neutropenia. CAR-T cell therapy also targets CD19 (tisagenlecleucel, axicabtagene β€” for relapsed/refractory ALL, DLBCL). Obinutuzumab = glycoengineered anti-CD20 (CLL). Ofatumumab = fully human anti-CD20.
✘ A/B/D wrong: Other targets.
82
Immune checkpoint inhibitors (ICIs): Most Probable
  • ABlock cell wall synthesis
  • BDNA synthesis inhibitors
  • CHormonal agents
  • DBlock inhibitory immune checkpoints

πŸ“˜ Explanation

βœ” Correct β€” D: ICIs: PD-1 β€” pembrolizumab (Keytruda), nivolumab (Opdivo), cemiplimab; PD-L1 β€” atezolizumab, durvalumab, avelumab; CTLA-4 β€” ipilimumab; LAG-3 β€” relatlimab. Combinations (ipi-nivo): better response in some melanoma. Biomarkers: PD-L1 expression (variable predictive value), TMB (tumour mutational burden), MSI-high/dMMR, specific gene signatures. ADR: IMMUNE-RELATED adverse events (irAEs) β€” hypothyroidism, colitis, pneumonitis, hepatitis, endocrinopathies (hypophysitis, T1DM), nephritis, rash, myocarditis (rare but lethal); managed with high-dose steroids Β± secondary immunosuppression. Allison + Honjo β†’ Nobel 2018.
✘ A/B/C wrong: Not ICI mechanism.
83
Tamoxifen in ER+ breast cancer: GPAT 2018
  • AAromatase inhibitor
  • BSelective estrogen
  • CGnRH antagonist
  • DAlkylator

πŸ“˜ Explanation

βœ” Correct β€” B: Tamoxifen β€” 5-10 years adjuvant; chemoprevention in high-risk women. Raloxifene = SERM used in osteoporosis + breast cancer prevention (no endometrial risk, but can cause VTE). Fulvestrant = pure ER antagonist (no agonist activity anywhere; monthly IM in metastatic ER+ breast). Aromatase inhibitors (AIs) β€” for postmenopausal: anastrozole, letrozole (non-steroidal competitive); exemestane (steroidal irreversible). More effective than tamoxifen in postmenopausal but cause osteoporosis + joint pain (no endometrial Ca risk). Combined with CDK4/6 inhibitors (palbociclib, ribociclib, abemaciclib) β€” standard for ER+/HER2- metastatic. GnRH agonists (leuprolide, goserelin) β€” ovarian suppression in premenopausal.
✘ A/C/D wrong: Different classes.
84
Etoposide mechanism: GPAT 2020
  • ATopoisomerase II inhibitor
  • BMicrotubule inhibitor
  • CAntimetabolite
  • DAlkylator

πŸ“˜ Explanation

βœ” Correct β€” A: Etoposide (VP-16), teniposide (VM-26) = Topo II inhibitors. Similar actions to anthracyclines at the topo II level but without DNA intercalation. ADR: myelosuppression, hypotension during infusion (rapid administration), alopecia, secondary MLL-rearranged AML (t(11q23) translocation β€” ~ 1 %). Topo I inhibitors (also plant-derived, from Camptotheca acuminata): topotecan (ovarian, SCLC), irinotecan (colorectal β€” FOLFIRI; CPT-11 β†’ active SN-38; UGT1A1*28 pharmacogenetics); severe diarrhoea (cholinergic acute, SN-38-induced delayed).
✘ B/C/D wrong: Wrong classes.
85
Bleomycin signature ADR: Most Probable
  • ACardiotoxicity
  • BOtotoxicity
  • CPulmonary fibrosis
  • DHaemorrhagic cystitis

πŸ“˜ Explanation

βœ” Correct β€” C: Bleomycin = glycopeptide antitumour antibiotic (Streptomyces verticillus); binds DNA + Fe(II) β†’ oxygen radicals β†’ DNA strand breaks. Uses: Hodgkin (ABVD), testicular (BEP), Kaposi sarcoma, squamous cell carcinomas. Pulmonary fibrosis β€” progressive, frequently fatal. Minimal myelosuppression (unique β€” used in combinations). Monitor baseline + periodic lung function. Limit cumulative dose. Caution: supplemental O2 during anaesthesia + surgery can precipitate fatal ARDS years after treatment.
✘ A wrong: Anthracyclines.
✘ B wrong: Cisplatin.
✘ D wrong: Cyclophosphamide.
86
L-asparaginase is used in: Most Probable
  • AAcute lymphoblastic
  • BBreast cancer
  • CLung cancer
  • DProstate cancer

πŸ“˜ Explanation

βœ” Correct β€” A: L-asparaginase (Erwinase from Erwinia / E. coli enzyme / PEG-asparaginase) β€” pediatric ALL induction + intensification. Unique mechanism β€” antimetabolite-like but depletes extracellular amino acid. ADR: hypersensitivity (β†’ switch formulation); pancreatitis (acute β€” stop drug permanently in some protocols); coagulopathy (↓ antithrombin III, fibrinogen, factors) β†’ thrombosis or bleeding; hyperglycaemia; CNS symptoms (hyperammonaemia). PEG-asparaginase (pegaspargase/Oncaspar/Asparlas) β€” longer half-life, less immunogenic.
✘ B/C/D wrong: Not indications.
87
Thalidomide & lenalidomide in multiple myeloma act as: Most Probable
  • AAlkylators
  • BImmunomodulatory drugs
  • CAntimetabolites
  • DMicrotubule inhibitors

πŸ“˜ Explanation

βœ” Correct β€” B: IMiDs era (thalidomide β†’ lenalidomide β†’ pomalidomide β†’ iberdomide/CC-220). MM regimens: VRd (bortezomib-lenalidomide-dex), DVd (daratumumab-velcade-dex), KRd (carfilzomib-lenalidomide-dex), IXAZOMIB-Rd, ISA-Kd. ADR: thromboembolism (pretreat with aspirin / LMWH); neutropenia (lenalidomide more than thalidomide); rash, fatigue, peripheral neuropathy (thalidomide ↑↑), teratogenicity. Revlimid REMS + registries. Proteasome inhibitors: bortezomib (reversible), carfilzomib, ixazomib (oral) β€” also used in MM.
✘ A/C/D wrong: Not IMiD mechanism.
88
Interferon-Ξ± in cancer is mainly used for: Most Probable
  • ABreast cancer
  • BColorectal cancer
  • CChronic hepatitis B
  • DLung cancer

πŸ“˜ Explanation

βœ” Correct β€” C: IFN-Ξ± (IFN alfa-2b, peg-IFN) β€” mechanism: binds IFN-Ξ± receptor β†’ JAK-STAT pathway β†’ upregulates ISGs (interferon-stimulated genes) β†’ antiviral + antiproliferative + immunomodulatory. Almost obsolete for hepatitis C (DAAs replaced). Still used: hepatitis B (finite therapy option alongside tenofovir/entecavir); hairy cell leukaemia + PV (IFN-Ξ±-2b, peg-IFN); Kaposi sarcoma; renal cell cancer (2nd-line). ADR: flu-like symptoms, depression (suicide), autoimmune disorders (thyroid, diabetes), neutropenia, cardiotoxicity, retinopathy.
✘ A/B/D wrong: Not standard indications.
89
BCG (Bacillus Calmette-GuΓ©rin) intravesical use: Most Probable
  • ANon-muscle invasive
  • BSystemic leukaemia
  • CBreast cancer
  • DProstate cancer

πŸ“˜ Explanation

βœ” Correct β€” A: BCG = live attenuated M. bovis. Approved use: (1) TB vaccination (intradermal, neonatal in high-TB countries); (2) intravesical for NMIBC (high-grade Ta/T1, CIS) β€” induction 6 weekly + maintenance; standard of care after TURBT. Mechanism involves activation of macrophages, T cells, NK cells in bladder mucosa. Contraindications: active TB, immunosuppression, HIV, traumatic catheterisation (risk of BCG sepsis). Global shortage periodically. Chemotherapy alternatives: mitomycin C, gemcitabine intravesical.
✘ B/C/D wrong: Other cancers.
90
CAR-T cell therapy targets in B-cell ALL & DLBCL: Practice Question
  • ACD20
  • BCD19
  • CHER2
  • DCD3

πŸ“˜ Explanation

βœ” Correct β€” B: CAR-T = Chimeric Antigen Receptor T-cells: patient T-cells engineered ex vivo to express CAR (scFv + costimulatory CD28/4-1BB + CD3ΞΆ) β†’ infused β†’ recognise & kill target-expressing cells. Indications: R/R pediatric ALL, DLBCL, primary mediastinal B-cell lymphoma, follicular lymphoma, mantle cell lymphoma, multiple myeloma. Major toxicities: cytokine release syndrome (CRS β€” treat with tocilizumab, anti-IL-6R); immune-effector cell-associated neurotoxicity syndrome (ICANS β€” steroids); on-target off-tumour effects; B-cell aplasia (IVIG replacement). Cost ~ β‚Ή3-4 crore per patient. India: NexCAR19 (indigenous, 2023, ~ β‚Ή30 lakh).
✘ A/C/D wrong: Other mAb targets.

πŸ’‘ GPAT MEDICINAL CHEM III β€” HIGH-YIELD LAST-MINUTE TIPS

Ξ²-Lactams: 6-APA (penicillin) / 7-ACA (cephalosporin) / carbapenem / monobactam (aztreonam). Gen: penicillin G/V / amp-amox / methicillin-oxa / ticar-pipera. Ceph 1st (cefaz/lex) - 5th (ceftaroline - MRSA). Ξ²-lactamase inhibitors: clav, sulbactam, tazobactam, avibactam, vabor.

Protein synthesis: 30S: aminoglycosides, tetracyclines, tigecycline. 50S: macrolides, clindamycin, chloramphenicol, linezolid, streptogramins.

Quinolones: Target DNA gyrase + topo IV. Avoid: tendinopathy, QT, peripheral neuropathy, aortic aneurysm (FDA black-box).

Anti-TB: HRZE (2m) + HR (4m); INH activated by KatG; RIF rpoB; PZA pncA; EMB optic neuritis. MDR: BPaLM 6m.

Antifungals: Polyenes (AmB) bind ergosterol. Azoles inhibit CYP51. Echinocandins block Ξ²-1,3-glucan. Terbinafine inhibits squalene epoxidase. 5-FC β†’ 5-FU.

Antivirals: ACV (HSV/VZV), ganciclovir (CMV); oseltamivir (neuraminidase); remdesivir (SARS-CoV-2 RdRp); DAAs for HCV ("buvir/asvir/previr"); NRTIs + INSTIs cornerstone for HIV.

Antimalarials: Chloroquine (obsolete for falciparum); ACT first-line falciparum; primaquine radical cure P. vivax.

Anti-cancer: CLS β€” Alkyl (cyclo, cispl), Antimet (MTX, 5-FU), Antibio (doxo, bleo), Plant (vinca, taxol, etopo), TKI, mAb, IMiDs, ICIs. ADR rules: doxo cardio, bleo lung, cyclo urinary, cisp renal+oto, vincr nerve, taxol allergy + nerve.

πŸ‘¨β€πŸ« Authored & Developed By

Mr. K. Mallikarjuna Reddy

Associate Professor, M. Pharma (Pharmacology)

πŸ›οΈ Institution

Vasantidevi Patil Institute of Pharmacy

Kodali, Maharashtra, India

πŸ“¬ Contact & Web

πŸ“§ mallikaphd@gmail.com

🌐 kmradvice.com

πŸ“š GPAT Question Bank Β· Vasantidevi Patil Institute of Pharmacy Β· Kodali, Maharashtra Β· For PCI B.Pharm Curriculum